Departmental Groups
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- (Chem Eng)
- (Elec Eng)
- (at NYU)
Interdisciplinary Research
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Paul Chaikin
Professor Chaikin is Professor Emeritus at Princeton, currently teaching at NYU.
"Soft and Hard Condensed Matter" We are
engaged in many experimental investigations in "Hard"
(quantum electronic physics, and low temperature physics)
and "Soft" (statistical mechanics of phase transitions,
colloids, polymers, hydrodynamics) condensed matter. And in
many case we sit at the interface, using physics and
techniques from one sub field in the other.
Colloids - Colloids, either hard spheres or
charged
polystyrene spheres in aqueous suspension- Polyballs with
sufficiently strong
interactions that they can crystallize at room temperature.
Since we can
control the strength and range of the interactions as well
as the particle
densities, these are ideal model systems to study solids,
liquids, glasses,
compounds, thermodynamic transitions, elasticity, viscosity,
diffusion,
hydrodynamic instabilities and nonlinear flow. Gravitational
effects are
balanced with a counterflow of solvent (the world's slowest
fluidized
bed), or removed by performing experiments in space. We
study these
phenomena using light and x-ray scattering, digital imaging,
microscopy, laser tweezers and
mechanical measurements. This research is a collaborative
endeavor with the group of Prof. W. B. Russel in Chemical
Engineering. Our aim is both the understanding of very
fundamental problems, such as the liquid-solid transition,
the existence of glasses, the effects of long range
hydrodynamic interactions and the use of these techniques
for colloidal architecture to create new and unusual
structures. Our experiments have flown on several space
shuttle microgravity missions and we have a continuing
effort devoted to colloids, complex fluids microscopic
manipulation in microgravity.
Nano-Lithography with diblock copolymers:
Diblock copolymers consist of two segments of incompatable
polymers A-A-A--A-, and -B--B-B-B chemically bound at one of
their ends. The separate polymers would phase separate (like
oil and water) but they are tied together. The best they can
do is microphase separate into A rich and B rich regions
which form periodic lamella, cylinders in a hexagonal
pattern or spheres on an FCC lattice (along with more exotic
phases).The periodicities are typically on the scale of 5-50
of nanometers. We have been studying thin films of these
materials for use in lithography on a density and spacing
scale unavailable with any present technology. For example
we have been able to produce periodic dots, and holes which
cover a semiconductor at a density of 3x1012 (3 trillion)
for a 3 inch wafer. The fundamental aspects of this study
involve how ordered structures evolve from disorder in two
dimensions. There is both orientational and periodic order
that appears in the crystalline and liquid crystalline
patterns that the diblocks form. And a variety of
experimental techniques allow us to study how defects
(dislocations and disclinations) can rearrange in response
to temperature and applied fields.
Low dimensional strongly correlated electron
systems The family of quasi-one-dimensional
layered superconductors (e.g.
(TMTSF)2PF6) are probably the most
interesting electronic materials ever discovered. As
temperature, pressure and magnetic field are changed, this
material is a metal, semi-metal, semi-conductor, insulator,
antiferromagnetic, and
superconducting and exhibits nonlinear spin density wave
transport,
spectacular angular dependent magnetoresistance and the
Quantum Hall
Effect. Recently discovered phenomena include decoupling of
the layers by application of a parallel magnetic field,
transitions from metallic to insulating states as the
magnetic field is rotated relative to the crystal axes,
non-Fermi liquid effects and triplet superconductivity. The
experimental techniques employed in these studies involve,
high pressure, high magnetic fields (sometimes at the
National High Magnetic Field lab), low temperatures,
transport, thermal, magnetic, elastic and NMR meaurements.
These techniques are also applied to other strongly
correlated systems.
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S e l e c t e d P u b l i c a t i o n s:
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- "Principles of
condensed matter physics", P. M. Chaikin and T. C. Lubensky, Cambridge
University Press (Cambridge, 1995)
- "Crystallization of Hard Sphere Colloids in
\mu - Gravity", J. Zhu, M. Li, W. Meyer, R. H. Ottewill, STS-73
Space Shuttle Crew, W. B. Russel, P. M. Chaikin, Nature
387 883 (1997).
- "Long-Range Correlations in Sedimentation", P. N.
Segre, E. Herbolzheimer and P. M. Chaikin, , Phys. Rev.
Lett. 79 2574 (1997).
- "Block Copolymer-Lithography: Periodic Arrays of
~1011 Holes in 1 Square Centimeter", Miri Park, C.
Harrison, P. M. Chaikin, R. A. Register, and
D. H. Adamson, Science 276 1401
(1997).
- "Depth Profiling Block Copolymer
Microdomains", C. Harrison, M. Park, P. Chaikin, R. A.
Register, D. H. Adamson and N. Yao, Macromolecules
31, 2185 (1998).
- "Magic Angles and the Ground States in
(TMTSF)2PF6, E. I. Chashechkina,
and P. M. Chaikin, Phys. Rev.
Lett. 80, 2181 (1998).
- "The Quantum-Classical Metal", D.G. Clarke, S. P.
Strong, P. M. Chaikin, E. I. Chashechkina, Science
279, 2071 (1998).
- "Layer by Layer Imaging of Diblock Copolymer Films with
a Scanning Electron Microscope", C. Harrison, M. Park, R.A. Register,
D.H. Adamson, and N. Yao, Polymer
39 2733 (1998)
- Z. Cheng, W.B. Russel, and P.M. Chaikin "Controlled
growth of hard-sphere colloidal crystals", Nature 401,
893 - 895 (1999).
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